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The selenium analogue of Lawesson's reagent, [PhP(Se)(μ-Se)]2 is an effective reagent for synthesizing N,N-disubstituted selenoamides. The reaction is carried out under mild conditions (room temperature) and affords the selenoamide in higher yield than using other selenation reagents.The selenium analogue of Lawesson's reagent, [PhP(Se)(μ-Se)]2 is an effective reagent for synthesizing N,N-disubstituted selenoamides.