The IPB has once again been recognized for its exemplary actions in terms of equal opportunity-oriented personnel and organizational policies and has received the TOTAL E-QUALITY certification for the…
The Plant Science Student Conference (PSSC) has been organised by students from the two Leibniz institutes, IPK and IPB, every year for the last 20 years. In this interview, Christina Wäsch (IPK) and…
Heinke, R.; Arnold, N.; Wessjohann, L.; Schmidt, J.;Negative ion tandem mass spectrometry of prenylated fungal metabolites and their derivativesAnal. Bioanal. Chem.405177-189(2013)DOI: 10.1007/s00216-012-6498-1
Liquid chromatography negative ion electrospray ionisation tandem mass spectrometry has been used for characterisation of naturally occurring prenylated fungal metabolites and synthetic derivatives. The fragmentation studies allow an elucidation of the decomposition pathways for these compounds. It could be shown, that the prenyl side chain is degraded by successive radical losses of C5 units. Both the benzoquinones and the phenolic derivatives display significant key ions comprising the aromatic ring. In some cases, the formation of significant oxygen-free key ions could be evidenced by high-resolution MS/MS measurements. Furthermore, the different types of basic skeletons, benzoquinones and phenol type as well as cyclic prenylated compounds, can be differentiated by their MS/MS behaviour.
Publications
Sinz, A.; Schmidt, J.;Forty-third annual meeting of the German Society for Mass SpectrometryAnal. Bioanal. Chem.3982777-2778(2010)DOI: 10.1007/s00216-010-4216-4