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Reisberg, M.; Arnold, N.; Porzel, A.; Neubert, R. H.; Dräger, B.; Malusides, novel glucosylceramides isolated from apple pomace (Malus domestica) Z. Naturforsch. C 73, 33-39, (2018) DOI: 10.1515/znc-2017-0059
Three new glucosylceramides (GluCers) named malusides I–III (1–3) were isolated from apple (cultivars of Malus domestica) pomace (fruit material remaining after juice extraction). An unusual oxo/hydroxy group pattern within the sphingadienine (d18:2) type sphingoid base was observed. All compounds contained the same α-hydroxylated fatty acid (h16:0) and a β-D-glucose moiety. Their structures were assigned on the basis of one- and two-dimensional (1D and 2D) nuclear magnetic resonance (NMR) spectroscopic analyses and mass spectrometry (MS) measurements.
